Effect of pH Value on the Micro-structures and Optical Properties of Nano-crystalline CuInS2 by Solvothermal Method
来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition2010年第3期
论文作者:冯嘉敏 韩建军
文章页码:399 - 402
摘 要:Copper indium disulfide(CuInS2) nano-particles were synthesized by solvothermal method at 150 ℃ using copper(?) chloride,indium(Ш) chloride,thiourea and ethanol as raw materials,and characterized by X-ray diffraction(XRD),field-emission scanning electron microscope(FESEM),and UV-Vis spectra.The effects of pH value on its micro-structures and optical properties were investigated.The results show that,with the pH value increasing,the particle size of the nano-crystalline CuInS2 increases,and its band gap becomes narrower under alkaline condition.The band gaps of CuInS2 nano-particles are from 1.52 eV to 1.93 eV,which makes them promising candidates as absorber materials for photovoltaic applications.
冯嘉敏,韩建军
摘 要:Copper indium disulfide(CuInS2) nano-particles were synthesized by solvothermal method at 150 ℃ using copper(?) chloride,indium(Ш) chloride,thiourea and ethanol as raw materials,and characterized by X-ray diffraction(XRD),field-emission scanning electron microscope(FESEM),and UV-Vis spectra.The effects of pH value on its micro-structures and optical properties were investigated.The results show that,with the pH value increasing,the particle size of the nano-crystalline CuInS2 increases,and its band gap becomes narrower under alkaline condition.The band gaps of CuInS2 nano-particles are from 1.52 eV to 1.93 eV,which makes them promising candidates as absorber materials for photovoltaic applications.
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