图书来源:二元合金相图及中间相晶体结构 二元合金相图及中间相晶体结构
作 者:唐仁政 田荣璋
出版时间:2009-05
定 价:320元
图书ISBN:978-7-81105-831-4
出版单位:中南大学出版社
Qingchun Yu1), Shichao Zhang2), Xindong Wang1), Jie Zhang3), and Zhenming Lu3) 1) School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China 2) Materials Science and Engineering School, Beijing University of Aeronautics and Astronautics, Beijing 100083, China 3) Institute of Nuclear and Energy Technology, Tsinghua University, Beijing 102201, China
摘 要:CuO/γ-Al2O3 has been considered as a promising and recycling sorbent to remove sulfur dioxide from flue gas. In this study, a series of CuO/γ-Al2O3 sorbents with different CuO loadings were prepared by impregnation. The monolayer coverage of CuO supported on γ-Al2O3 determined by X-ray quantitative analysis was 0.275 g CuO/g (γ-Al2O3). Below the monolayer coverage, CuO was found highly dispersed on γ-Al2O3. Thermogravimetric technique was used to study sulfation kinetics and sulfation recycling. It was found that the Langmuir kinetic adsorption model described well the experimental data at the rapid sulfation region of the CuO/γ-Al2O3 sorbent. The adsorption activation energy was 19.98 kJ/mol and the pre-exponential factor was 9.97×10-5 s-1-Pa-1. The CuO/γ-Al2O3 sorbent has shown good performance on regeneration, but long sulfation time might cause the deactivation of the CuO/γ-Al2O3 sorbent. It was also seen that the sulfated γ-Al2O3 support could not be reduced at 400°C.
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