含硅抑制剂对钛辉石的抑制作用

来源期刊:中国有色金属学报2010年第12期

论文作者:张国范 马军二 朱阳戈 冯其明 王维清

文章页码:2419 - 2424

关键词:钛铁矿;钛辉石;抑制剂;浮选;水玻璃

Key words:ilmenite; titanaugite; depressants; flotation; water glass

摘    要:研究了在油酸钠为捕收剂的浮选体系中,两种含硅抑制剂氟硅酸钠和水玻璃对微细粒钛铁矿与钛辉石浮选行为的影响。在实际矿石试验中,以水玻璃作为抑制剂且在弱酸性条件下(pH=5~6)成功实现钛铁矿与钛辉石的浮选分离,并通过吸附量测试、X射线光电子能谱(XPS)测试分析了水玻璃选择性分离钛铁矿的作用机理。结果表明:水玻璃对油酸钠在钛铁矿表面吸附影响小,却能在较大程度上降低油酸钠在钛辉石表面的吸附量,这为两种矿物的分离提供依据。其主要原因在于水玻璃能够与钛辉石表面的Mg、Fe和Al原子发生化学键合,增加钛辉石的亲水性,从而减少捕收剂在其表面的吸附。

Abstract: Using sodium oleate as collector, the effects of sodium fluorosilicate and water glass on floatation behavior of fine ilmenite and titanaugite were investigated. The results show that, using the water glass as depressant in the weak acidic system with pH of 5-6, the ilmenite and titanaugite can be successfully separated by flotation in practical ore experiment. The results of adsorption measurements and X-ray photoelectron spectroscopy (XPS) show that the mechanism of selective separation of ilmenite by the water glass, namely, the water glass can effectively prevent the adsorption of sodium oleate onto the surface of titanaugite, while it shows little effect on the adsoption of sodium oleate onto ilmenite, which is the basis for flotation separation of both of minerals. Above-mentioned mechanism comes from the formed chemical bonds between the water glass and Fe,Mg and Al atoms on the surface of titanaugite, which effectively increases the hydrophilicity of titanaugite, as a result, reducing the adsorption of collector on titanaugite.

基金信息:国家重点基础研究发展计划资助项目
2009年博士点基金资助项目
湖南省研究生科研创新资助项目

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