Selective flotation separation of andalusite and quartz and its mechanism

Yan-ping Niu^1,2,3，Chuan-yao Sun²，Wan-zhong Yin¹，Xing-rong Zhang²，Hong-feng Xu⁴

1. College of Resources and Civil Engineering, Northeastern University2. State Key Laboratory of Mineral Processing,BGRIMM Technology Group4. Heilongjiang Mining Group Co.Ltd.

摘 要：The separation of andalusite and quartz was investigated in the sodium oleate flotation system, and its mechanism was studied by solution chemical calculation, zeta-potential tests, Fourier transform infrared spectroscopic（FTIR）, and X-ray photoelectron spectroscopic（XPS）. The flotation tests results show that FeCl₃·6H₂O has a strong activation effect on andalusite and quartz and citric acid has a strong inhibitory effect on activated quartz, thus increasing the floatability difference between quartz and andalusite when the pulp p H is approximately 8. The FTIR, Zeta potential, and XPS analyses combined with the chemical calculation of flotation reagent solutions demonstrate that Fe forms hydroxide precipitates on the surface of andalusite and quartz and that oleate anions and metal ions adsorb onto the surface of the minerals. The elements Al and Fe can be chemically reacted. The anions in citric acid have different degrees of dissolution of Fe on the andalusite and quartz surfaces, thereby selectively eliminating the activation of the elemental Fe on andalusite and quartz and increasing the floatability of andalusite, leading to a better separation effect between andalusite and quartz.

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