基于Box-Behnken设计优化铝土矿选矿回水处理工艺参数
来源期刊:中国有色金属学报(英文版)2019年第4期
论文作者:霍强 刘晰 陈黎军 吴永宏 武海艳 谢建平 刘新星 邱冠周
文章页码:821 - 830
关键词:回水处理;铝土矿浮选;聚合氯化铝铁;Box-Behnken设计
Key words:backwater treatment; bauxite flotation; polyaluminum ferric chloride; Box-Behnken design
摘 要:随着铝土矿浮选回水循环时间的增加,铝土矿浮选指标逐渐降低,而浮选回水的外排会带来一定的环境风险。采用Fenton氧化、吸附、混凝等方法处理浮选回水,测定处理后浮选回水的浮选指标,并采用Box-Behnken设计(BBD)对主要试验参数进行优化。结果表明,聚合氯化铝铁对混凝处理后的浮选指标有明显的改善作用。BBD预测的最佳参数值为pH 7.55、聚合氯化铝铁用量1.09 g/L、温度25 °C。在预测的最佳工艺参数下,精矿氧化铝回收率82.83%、尾矿铝硅比为 1.30,结果与预测值的偏差均小于3%,这表明BBD适用于选矿回水处理中关键参数的优化预测。
Abstract: Flotation indexes gradually decrease with the increase of cycle time of the backwater in bauxite floatation, and discharge of backwater brings environmental risk. In this study, methods such as Fenton-oxidation, adsorption and coagulation were used in the treatment of backwater, the flotation indexes were checked after backwater treatments, and Box-Behnken design (BBD) was used in the optimization of the main operating parameters. The results reveal that flotation indexes are effectively improved after coagulation treatment by polyaluminum ferric chloride (PAFC). The optimum parameters predicted by BBD are pH 7.55, 1.09 g/L PAFC dosage and temperature of 25 °C. Under these optimum conditions, a maximum recovery of Al2O3 of 82.83% and a minimum A/S of 1.30 of tailings are gained, while the deviations are less than 3% from the predicted values. These findings encourage the application of BBD for the optimization of critical parameters in backwater treatment.
Trans. Nonferrous Met. Soc. China 29(2019) 821-830
Qiang HUO1,2, Xi LIU3, Li-jun CHEN1, Yong-hong WU1,2, Hai-yan WU1,2, Jian ping XIE1,2, Xin xing LIU1,2, Guan-zhou QIU1,2
1. School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China;
2. Key Laboratory of Biohydrometallurgy, Ministry of Education, Central South University, Changsha 410083, China;
3. Zhengzhou Non-ferrous Metals Research Institute Co. Ltd. of CHALCO, Zhengzhou 450041, China
Received 7 May 2018; accepted 15 January 2019
Abstract: Flotation indexes gradually decrease with the increase of cycle time of the backwater in bauxite floatation, and discharge of backwater brings environmental risk. In this study, methods such as Fenton-oxidation, adsorption and coagulation were used in the treatment of backwater, the flotation indexes were checked after backwater treatments, and Box-Behnken design (BBD) was used in the optimization of the main operating parameters. The results reveal that flotation indexes are effectively improved after coagulation treatment by polyaluminum ferric chloride (PAFC). The optimum parameters predicted by BBD are pH 7.55, 1.09 g/L PAFC dosage and temperature of 25 °C. Under these optimum conditions, a maximum recovery of Al2O3 of 82.83% and a minimum A/S of 1.30 of tailings are gained, while the deviations are less than 3% from the predicted values. These findings encourage the application of BBD for the optimization of critical parameters in backwater treatment.
Key words: backwater treatment; bauxite flotation; polyaluminum ferric chloride; Box-Behnken design
1 Introduction
Ore grade decreases because of the sharp and increasing demand of bauxite [1]. More than 98% of the bauxite ores in China are of the diasporic type, having characteristics of complex mineral composition, low A/S (mass ratio of Al2O3 to SiO2) and difficulty to be processed. The flotation method has been successfully industrialized for obtaining concentrates with an increased A/S that could be processed directly by the Bayer process, and this has made a great contribution to the sustainable development of China’s aluminum industry [2,3]. A large amount of water was saved by recycling through the flocculation and sedimentation of the ore pulp [4]. In industrial production, flotation indexes gradually decreased with the increase of cycle time of the backwater in bauxite floatation [5,6]. The bauxite flotation plants in China, most of which were built and put into production after 2009, retained good flotation indexes by discharging the backwater out of the recycling system and replacing it with fresh water. There are no reports on research and industrial applications of backwater treatment of bauxite flotation.
There were some organic pesticide residues in backwater, such as hydrolyzed polyacrylamide (HPAM). HPAM itself had no toxicity; however, it had been reported to be easily broken down by physical-chemical factors, and its intermediate products were hazardous because their monomer was highly toxic [7]. Therefore, the discharge of backwater brought potential environmental risk [8], but no studies have focused on that problem yet.
Treatment of backwater would improve the flotation indexes, increase the utilization rate of water resources and contribute much to the aluminum industry, while the environmental risk brought by the discharge of backwater was eliminated. In this study, in order to investigate an effective method for backwater treatment, a series of methods were used to treat the backwater, which had poor flotation indexes, and the Box-Behnken design (BBD) for experiments was adapted from the response surface methodology (RSM) to optimize the relevant operating parameters in order to reduce the researcher’s experimental workload and high cost of chemical usage and to avoid uncertainty in industrial application [9,10].
2 Experimental
2.1 Materials
2.1.1 Water in tests
Fresh water was used in the control group. Backwater for tests was collected from the backwater basins at a bauxite flotation plant in Henan Province, China. The pH value of the backwater was 8.81, and the major chemical element analysis results are listed in Table 1.
Table 1 Major chemical element analysis results of backwater (mg/L)
2.1.2 Ore for tests
Bauxite ore for tests was collected from the homogenization yard in the bauxite flotation plant. The results from the chemical element analysis and mineral phase analysis of the ore are shown in Tables 2 and 3, respectively.
Table 2 Chemical element analysis results of bauxite ore (wt.%)
Table 3 Mineral phase analysis results of bauxite ore (wt.%)
2.2 Methods
2.2.1 Backwater treatment
(1) Control group: Flotation tests on fresh water were carried out as a blank control, and flotation tests on untreated backwater were carried out as a basic control.
(2) Ions influence group: Flotation tests on water to which was added analytic reagents such as CaCl2, Fe2SO4, Na2SO4, KCl, NaF, and NaCl into distilled water were carried out to examine the influence of the ions in backwater. The ion concentrations of water added to ions were 1.62 mg/L Fe2+, 54.05 mg/L Ca2+, 2.00 mg/L Mg2+, 13.60 mg/L K+, 93.51 mg/L SO42-, 121.69 mg/L Cl- and 6.79 mg/L F-.
(3) Backwater treatment group: Treatment methods, including natural placement, adsorption by zeolite and activated carbon, coagulation by 5 g/L polyaluminum ferric chloride (PAFC) and 5 g/L polysilicate aluminum ferric (PSAF), were carried out under three pH values (5, 7 and 9), while treatments by the Fenton-oxidation method were carried out under the other three pH values (3, 4 and 5). Flotation tests were carried out using the backwater after treatment.
2.2.2 Flotation test
Flotation tests [11] were performed in a flotation cell with a flotation volume of 1.5 L and were carried out under the industrial conditions of grinding fineness of 92.69% <0.074 mm, pulp density of 31%, pH value of 9.3, and temperature of 25 °C. A flowsheet of the flotation tests is shown in Fig. 1.
NaCO3, NaOH and HCl were used as pH modifiers. The collector used in flotation tests was a mixture of saponified oleic acid and benzohydroxamic acid.
Fig. 1 Flowsheet of flotation tests
2.2.3 Measurements
Degree of dissociation of grinding products was determined using quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) [12]. The flotation indexes of the treated backwater, including recovery of Al2O3 and A/S of tailings, were used to characterize the effect of the backwater treatment.
2.2.4 Box-Behnken design
Backwater treatment was optimized by response surface methodology (RSM) using the BBD. The statistical software Minitab 17.1.0 was used for the analysis. Three independent parameters: pH (X1, 5-9); PAFC dosage (X2, 0.6-1.4 mL/L), and temperature (X3, 15-35 °C), were confirmed to optimize the backwater treatment, which was characterized by flotation indexes (Y1 for recovery of Al2O3 and Y2 for A/S of tailings). The coded and uncoded levels of these variables are presented in Table 4. The optimum response and the corresponding process parameters were also determined.
3 Results and discussion
3.1 Results of QEMSCAN
The distribution of main minerals of grinding products is indicated by area percent (AP, area ratio), which reveals the percentage of the particle area of diaspore to the total particle area. The results show that most diaspore particles with better dissociation were concentrated in fine-grained particles, whereas most diaspore particles with less than 50% dissociation were presented in coarse-grained particles. The percentage of coarse-grained particles should be reduced in the grinding process for the low dissociation and the complex association of minerals.
3.2 Flotation results
The reasons for the deterioration of the backwater flotation index, analyzed from the contact with the backwater, were mainly due to three aspects: the influence of the accumulation of ions brought into backwater by fresh water and ores, the influence of the accumulation of organics such as humus brought into backwater by ores, and the influence of the residual accumulation of HPAM added into the pulp of concentrates and tailings for the rapid settlement [13]. Therefore, three groups of experiments of backwater treatment, described in section 2.2.1, were carried out.
3.2.1 Flotation results for control group
As shown in Table 5, compared with the fresh water results, the backwater results had a decrease of 17.45% on recovery of Al2O3 and an increase of 0.98 on the A/S of tailings. In the backwater flotation system, the collection ability for diaspores was greatly reduced, resulting in the high A/S of the tailings and the low recovery of Al2O3.
Table 4 Box-Behnken design matrix
Table 5 Flotation results for control group
3.2.2 Results for ion influence group
Table 6 shows the flotation results of water added ions, which presented no obvious differences to those of fresh water.
Although studies suggested that Mg2+ advanced the dispersivity of bauxite, whereas Ca2+ and Fe2+ inhibited the dispersivity of bauxite [14], the results of this study indicated that the influence of ions in backwater was not the reason for the decrease in the flotation index because the concentrations of the ions hid not reached the upper limit.
3.2.3 Results for backwater treatment group
For the backwater treatment group, the results of the flotation tests, which were carried out after the backwater treatment, are shown in Fig. 2.
Table 6 Flotation results for influence group
Fig. 2 Flotation results of backwater treatment group
(1) Results for natural placement
As shown in Fig. 2(a), no improvements to the flotation indexes occurred in the natural placement group under all three pH values within 9 d, whereas small and similar improvements to the flotation indexes occurred in the natural placement group under all three pH values after 15 d. This indicated substances that affected the flotation indexes in the backwater degraded naturally with the prolongation of natural placement time. These results also indicated that ions in backwater were not the main reason for the decrease in flotation indexes.
(2) Results for Fenton-oxidation method
As shown in Fig. 2(b), flotation indexes had a small increase after the Fenton-oxidation method, and the effect became obvious with the increase in the dosage of Fenton reagents under all three pH values, which were represented with the increase in recovery of Al2O3 and the decrease in A/S of the tailings.
Fenton-oxidation, as a powerful method for removing almost any organic contaminant [15], has become one of the promising and alternative wastewater treatment methods [16]. In this study, under the treatment conditions of a pH value of 3 and Fenton reagent dosage up to 20 mmol/L, the best flotation index was only gained with the increase in recovery of Al2O3 of 5.52% and the decrease in A/S of the tailings of 0.33, which also had a large gap in comparison with that of fresh water. The Fenton-oxidation process, combined with hydrogen peroxide and ferrous ions, generated oxidation potential species such as the hydroxyl radical, which exhibited strong oxidation and could efficiently degrade the refractory organics, whereas studies showed that the removal rate of HPAM could reach more than 90% by Fenton-oxidation in the treatment of oilfield sewage [17]. However, the HPAM concentration of the backwater was in a low range, which might be due to the inefficiency of the Fenton-oxidation method in this study.
(3) Results for adsorption method
Adsorption is a method used to purify waste water by adsorbing the pollutants by adsorbents such as activated carbon and zeolite. Activated carbon is recognized as an effective and reliable means of removing impurities due to its tremendous adsorptive capacity [18], whereas zeolite is a silicoaluminate mineral with good stability and becomes the focus of intense interest due to the potentiality of the zeolite- mediated heterogeneous processes, exclusively featured by the high reactivity for complete elimination of recalcitrant pollutants and environmental remediation [19]. However, the results of this study (Figs. 2(c) and (d)) showed the lower effectiveness of the adsorption method executed both by activated carbon and zeolite and revealed that the adsorption method executed by activated carbon and zeolite did not adapt to the treatment of backwater of bauxite flotation.
(4) Results for coagulation method
The results for the coagulation by PAFC (Fig. 2(e)) showed that the flotation indexes gradually became better with the addition of PAFC dosage under the condition of pH=7, which were better than the indexes under the conditions of pH=5 and pH=9. Charge neutralization and the adsorption bridging effect between PAFC and HPAM were the primary flocculation mechanisms when the pH was adjusted to 7. The flotation indexes became stable when the PAFC dosage exceeded 0.6 mL/L, and good results were achieved, with 81.12% recovery of Al2O3 and 1.37 of A/S of the tailings, representing a 14.93% increase in the recovery of Al2O3 and a decrease of A/S of the tailings of 0.76 in comparison to that of backwater.
Similarly, the results of the coagulation by PSAF (Fig. 2(f)) showed that the flotation indexes gradually became better with the addition of PAFC dosage. An optimum result was reached under the condition of pH of 7 and PAFC dosage of 1.0 mL/L, with an increase in the recovery of Al2O3 of 12.75% and a decrease in A/S of the tailings of 0.60 in comparison with that of backwater.
The coagulation/flocculation method was widely used in wastewater treatment due to its capability for destabilizing and aggregating colloids [20,21]. There were two main types of coagulants, inorganic flocculants (such as PAC) and organic flocculants (such as PAM), each of which had its advantages and disadvantages. The main coagulant used in bauxite flotation plants was HPAM, and studies showed that flotation indexes would be affected by HPAM [22]. Combined with the results of QEMSCAN, high performance of sodium polyacrylate on flocculation for diaspore was due to interaction of carboxyl of sodium polyacrylate with active Al sets of diaspores by chemical absorption or the formation of hydrogen bonds via the hydroxyl groups of macromolecules with surface Al—OH to enhance the sedimentation rate of diaspores and destroy the flotation of diaspores [23]. Treatments of backwater by inorganic flocculants (PAFC and PSAF) obtained good results, primarily due to the incompatibility between inorganic flocculants and HPAM and the removal of HPAM after the addition of inorganic flocculants by the formation of the flocs [24].
3.3 Optimization by Box-Behnken design
3.3.1 Analysis of Box-Behnken design
In this study, the BBD was applied, and 15 experimental runs were conducted in random order to optimize backwater treatment by PAFC, which was characterized by recovery of Al2O3 (Y1) and A/S of Tailings (Y2) [25]. The effects of key parameters, pH (X1), PAFC dosage (X2) and temperature (X3), on backwater treatment were evaluated. The analysis of variance results are listed in Tables 7 and 8. According to the RSM results in regard to the response variables of the effect of backwater treatment, which were acquired from 15 groups of experiments with the help of Minitab 17 software, the regression analysis of data from Tables 7 and 8 resulted in the following quadratic expressions:
Y1=-9.41+18.86X1+27.22X2+0.456X3-1.2555X12-15.14X22-0.01450X32+0.372X1X2-0.0085X1X3+0.2350X2X3 (1)
Y2=5.772-0.889X1-2.049X2-0.0020X3+0.06198X12+1.253X22+0.000504X32-0.0313X1X2-0.00050X1X3-0.01812X2X3 (2)
Statistical testing was carried out by the calculated Fischer values (F-value) and probability values (p-value). The corresponding parameter is more significant if its p-value is smaller than 0.05 at a 95% confidence level [26]. Lack of fit was used to represent the degree of fit between the model and the actual experiment. The model was significant, and there was no missing factor when the p-value of lack of fit exceeded 0.05. A nonsignificant lack of fit was required to obtain an acceptable model.
Table 7 Analysis of variance for recovery of Al2O3 (Y1)
Table 8 Analysis of variance for A/S of tailings (Y2)
As shown in Table 7, regarding the analysis of variance for recovery of Al2O3, the model had a higher F-value of 71.29, which implied that the model was significant, and the probability that the F-value would occur due to noise was less than 0.1%. The independent variables of the linear model, pH (X1), PAFC dosage (X2) and temperature (X3), those of the quadratic model, pH (X12), PAFC dosage (X22) and temperature (X32), and the interaction model between PAFC dosage and temperature (X2X3) were quite significant because the p-values were less than 0.05, whereas the interaction between pH and PAFC dosage (X1X2) and the interaction between pH and temperature (X1X3) were not significant because the p-values exceeded 0.05. Judging by the F-values of the items in the regression model, the pH (X1) had the highest F-value (187.57), whereas the p-value was at a low level among other parameters, and, therefore, the degrees of importance of the three parameters on recovery of Al2O3 were ranked in the order pH (X1) > PAFC dosage (X2) > temperature (X3). The lack of fit F-value of 0.445 implied that lack of fit was not significant relative to the pure error. The R2 was 99.23%, and the adjusted R2 (R2(Adj)) was 97.83%, representing an excellent fit, and the predicted R2 (R2(Pred)) was 91.08%, which was in fair arrangement with the R2(Adj).
As shown in Table 8 for the analysis of variance for A/S of tailings, the model had a higher F-value of 26.02, which implied that the model was significant, and the chance for the F-value to occur due to noise was less than 0.1%. The independent variables of the linear model, pH (X1) and PAFC dosage (X2), the quadratic model, pH (X12), PAFC dosage (X22) and temperature (X32), and the interaction model between PAFC dosage and temperature (X2X3) were quite significant because the p-values were less than 0.05, whereas the linear model temperature (X3), the interaction between pH and PAFC dosage (X1X2) and the interaction between pH and temperature (X1X3) were not significant because the p-values exceeded 0.05. Judging by the F-values of the items in the regression model, the pH (X1) had the highest F-value (55.45), whereas the p-value was at a low level among other parameters, and, therefore, the degrees of importance of the three parameters on A/S of tailings were ranked in the order pH (X1) > PAFC dosage (X2) > temperature (X3). The lack of fit F-value of 0.445 implied that lack of fit is not significant relative to the pure error. The R2 was 0.9791, and the R2(Adj) was 0.9415, which represented a good fit, but the R2(Pred) was 0.6766, which meant some deviations with the R2(Adj).
3.3.2 Analysis by RSM
The significance of each of the three independent factors (pH, PAFC dosage and temperature) on recovery of Al2O3 (Y1) and A/S of Tailings (Y2) was revealed by illustrating the response surfaces as three dimensional (3D) plots (Fig. 3). The temperature was fixed at 25 °C (Figs. 3(a) and (d)), whereas the PAFC dosage and pH were kept constant at 1.09 mL/L (Figs. 3(b) and (e)) and 7.55 (Figs. 3(c) and (f)), respectively.
The variation in pH led to the steep climb and drop as shown in Figs. 3(a), (b), (d) and (e), whereas the gentle climb and drop appeared during the variations in PAFC dosage and temperature. Meanwhile, in Figs. 3(c) and (f), the variation in PAFC dosage dramatically affected recovery of Al2O3 and A/S of tailings, whereas the variation in temperature was less important. It can be seen that the variation in pH was more important than the other two factors for recovery of Al2O3 and A/S of tailings, whereas the variation in temperature gained the least contribution among the three factors.
3.3.3 Results of verification tests
The response optimization technique helped to identify a production of a combination of input variables that collectively optimized a single response or a set of responses [27]. By using response optimizer to identify the combination of predictor values that jointly optimize the recovery of Al2O3 (maximum) and the A/S of tailings (minimum), which were a pH of 7.55, PAFC dosage of 1.09 mL/L and temperature of 25 °C, with maximal recovery of Al2O3 of 83.28% and minimal A/S of tailings of 1.27.
As shown in Table 9, under optimal conditions proposed by response optimizer, 82.83% of the recovery of Al2O3 and 1.30 of the A/S of tailings were achieved (the average of three replicates), while the deviations between the actual and predicted values were both less than 3%. The predicted values were basically consistent with the measured values, indicating that the mathematical model established by RSM of BBD was powerful in prediction.
Fig. 3 3D surface plots of recovery of Al2O3 (Y1) as functions of pH and PAFC dosage (a), pH and temperature (b) and PAFC dosage and temperature (c); 3D surface plots of A/S of tailings (Y2) as functions of pH and PAFC dosage (d), pH and temperature (e) and PAFC dosage and temperature (f)
Table 9 Flotation results of backwater treated under predicted conditions
4 Conclusions
(1) Flotation indexes gradually decreased with the increase in cycle time of the backwater in bauxite floatation. Accumulation of the residual HPAM in backwater was the main reason for the decrease in flotation indexes.
(2) After the backwater was treated by PAFC, good flotation indexes were gained; this result was due to the reduction in the concentration of HPAM in the backwater for the incompatibility between PAFC and HPAM.
(3) The optimum parameter values were predicted to be a pH of 7.55, PAFC dosage of 1.09 mL/L and temperature of 25 °C by BBD. Under these optimum conditions, a maximum recovery 82.83% of Al2O3 and a minimum A/S 1.30 of tailings were gained. Both of the deviations were less than 3% with respect to the predicted values; these finding thus encourage the application of BBD for the optimization of critical parameters in backwater treatment.
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霍 强1,2,刘 晰3,陈黎军1,吴永宏1,2,武海艳1,2,谢建平1,2,刘新星1,2,邱冠周1,2
1. 中南大学 资源加工与生物工程学院,长沙 410083;
2. 中南大学 生物冶金教育部重点实验室,长沙 410083;
3. 中国铝业郑州有色金属研究院有限公司,郑州 450041
摘 要:随着铝土矿浮选回水循环时间的增加,铝土矿浮选指标逐渐降低,而浮选回水的外排会带来一定的环境风险。采用Fenton氧化、吸附、混凝等方法处理浮选回水,测定处理后浮选回水的浮选指标,并采用Box-Behnken设计(BBD)对主要试验参数进行优化。结果表明,聚合氯化铝铁对混凝处理后的浮选指标有明显的改善作用。BBD预测的最佳参数值为pH 7.55、聚合氯化铝铁用量1.09 g/L、温度25 °C。在预测的最佳工艺参数下,精矿氧化铝回收率82.83%、尾矿铝硅比为 1.30,结果与预测值的偏差均小于3%,这表明BBD适用于选矿回水处理中关键参数的优化预测。
关键词:回水处理;铝土矿浮选;聚合氯化铝铁;Box-Behnken设计
(Edited by Xiang-qun LI)
Foundation item: Project (1053320170205) supported by the Research and Innovation Project of Graduate Students of Central South University, China; Project (502211704) supported by the Fundamental Research Funds for the Central Universities, China; Project (SKL-SPM-201809) supported by the State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, China; Project (SKLAM005-2016) supported by the State Key Laboratory of Applied Microbiology Southern China; Projects (51320105006, 51504106, 51871250) supported by the National Natural Science Foundation of China; Project (2015FB204) supported by the Science and Technology Project of Yunnan Province, China
Corresponding author: Guan-zhou QIU; Tel: +86-731-88716592; E-mail: qgzcsu@126.com
DOI: 10.1016/S1003-6326(19)64992-7