Granular activated carbons from palm nut shells for gold di-cyanide adsorption
来源期刊:International Journal of Minerals Metallurgy and Materials2013年第2期
论文作者:William K.Buah Paul T.Williams
文章页码:172 - 179
摘 要:Granular activated carbons were produced from palm nut shells by physical activation with steam.The proximate analysis of palm nut shells was investigated by thermogravimetric analysis,and the adsorption capacity of the activated carbons,produced as a result of shell pyrolysis at 600 C followed by steam activation at 900 C in varying activation times,was evaluated using nitrogen adsorption at 77 K.Applicability of the activated carbons for gold dicyanide adsorption was also investigated.Increasing the activation hold time with the attendant increase in the degree of carbon burn-off results in a progressive increase in the surface area of the activated carbons,reaching a value of 903.1 m2/g after activation for 6 h.The volumes of total pores,micropores,and mesopores in the activated carbons also increase progressively with the increasing degree of carbon burn-off,resulting from increasing the activation hold time.The gold di-cyanide adsorption of the activated carbons increases with the rise of pore volume of the activated carbons.The gold di-cyanide adsorption of palm nut shell activated carbon obtained after 6-h activation at 900 C is superior to that of a commercial activated carbon used for gold di-cyanide adsorption.
William K.Buah,Paul T.Williams
Energy Research Institute,The University of Leeds,Leeds LS2 9JT,United Kingdom
摘 要:Granular activated carbons were produced from palm nut shells by physical activation with steam.The proximate analysis of palm nut shells was investigated by thermogravimetric analysis,and the adsorption capacity of the activated carbons,produced as a result of shell pyrolysis at 600 C followed by steam activation at 900 C in varying activation times,was evaluated using nitrogen adsorption at 77 K.Applicability of the activated carbons for gold dicyanide adsorption was also investigated.Increasing the activation hold time with the attendant increase in the degree of carbon burn-off results in a progressive increase in the surface area of the activated carbons,reaching a value of 903.1 m2/g after activation for 6 h.The volumes of total pores,micropores,and mesopores in the activated carbons also increase progressively with the increasing degree of carbon burn-off,resulting from increasing the activation hold time.The gold di-cyanide adsorption of the activated carbons increases with the rise of pore volume of the activated carbons.The gold di-cyanide adsorption of palm nut shell activated carbon obtained after 6-h activation at 900 C is superior to that of a commercial activated carbon used for gold di-cyanide adsorption.
关键词: