Phase transition of lithiated-spinel Li2Mn2O4 at high temperature
TANG Xin-cun(唐新村)1, 2, HUANG Bai-yun(黄伯云)2, HE Yue-hui(贺跃辉)2
1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China
Received 9 June 2005; accepted 26 September 2005
Abstract: The phase transition of Li2Mn2O4 spinel at high temperature was investigated by XRD, TG/DTA, average oxidation state of Mn and cyclic voltammeric techniques. The results reveal that the Li2Mn2O4 spinel is unstable. At high temperature, it is easy to transform into [Li2-2x]tet[Mn2-xLix]octO4, which accompanies the formation of Li2MnO3 impurities. The phase transition is associated with the transfer of Li+ from tetrahedral 8a sites to octahedral 16d sites. With the increasing sintering temperature from 450 ℃ to 850 ℃, the phase structure varies from lithiated-spinel Li2Mn2O4 to Li4Mn5O12-like to LiMn2O4-like and finally to rock-salt LiMnO2-like. In addition, a way of determining x with average oxidation state of Mn and the content of Li2MnO3 was also demonstrated.
Key words: lithium manganese oxide; Li2Mn2O4; phase transition; lithium-ion batteries
1 Introduction
Lithium manganese oxides are the most attractive cathode materials for rechargeable lithium-ion batteries because of their low-cost and less toxicity when compared with either cobaltates or nickelates[1-3]. Among these oxides, the spinel-framework compounds have been widely investigated due to scientific and commercial interest. In the ideal spinel LiMn2O4, Li and Mn respectively occupies tetrahedral 8a and octahedral 16d sites with space group Fd3m; and Li intercalates or deintercalates reversibly from 8a sites, which offers a theoretical capacity of 148 mAh/g with two charge/discharge plateaus at about 3.95 V and 4.15 V (vs Li+/Li). However, the poor rechargeability restricts its commercial applications. A number of studies have been done to improve its rechargeability, for example, by replacing Mn with other alloying elements[4, 5]. In particular, spinels Litet[Mn2-xLix]octO4, by replacing Mn with Li, have given rise to widely interests[6-8].
It is known that Li not only can substitute partially Mn in the octahedral 16d sites to form the manganese-absent spinels Litet[Mn2-xLix]octO4 (0≤x≤0.33) but also can further occupy the unoccupied tetrahedral 8a sites to form the lithium-rich spinels Li1+yMn2O4 (0≤y≤1). As a result, a series of spinel Li1+x+yMn2-xO4 compounds are given in the Li-Mn-O phase diagram with the average valent of Mn varied from 3 to 4[1, 9, 10]. For examples, at x = 0 and y = 1, the stoichiometric compound is the lithiated-spinel Li2Mn2O4 in which all Mn is trivalent, and it exhibits three voltage plateaus during the Li+ intercalation/ deintercalation respectively in about 3.0, 3.95 and 4.15 V[6, 11]; and at x = 0.33 and y = 0, the stoichiometric compound is given as Li4Mn5O12, in which all Mn is tetravalent; it offers a theoretical capacity of 163 mA·h/g in 3 V region and no capacity in the 4 V region[12-14]. From a structural point of view, when the oxidation state of Mn falls below 3.5, the Jahn-Teller distortion occurs and consequently deteriorates the rechargeability of spinel compounds. Thus, the spinels Li1+x+yMn2-xO4 with high values of x and low values of y (e.g. Li4Mn5O12) have been adapted to increase the average valence of Mn and further to improve the rechargeability. However, as suggested previously by various authors[7,12,14], the spinels Li1+x+yMn2-xO4 with high values of x are less thermo-stable than those with lower values of x at higher sintering temperature. For this purpose, the phase transition of the lithiated-spinel Li2Mn2O4 at high temperatures was investigated in this work.
2 Experimental
2.1 Preparation of lithium manganese oxide
LiMnC2O4(Ac) precursor was prepared by the method of the low-heating solid-state reaction as similar to the literature[15, 16]. The lithium manganese oxides were prepared by sintering the LiMnC2O4(Ac) precursor in air at different temperatures for 12 h with the heating rate of 10 ℃/min, without intermediate regrinding or other heating treatments.
2.2 Measurements and characterizations
The thermogravimetry (TG) and differential thermogravimetry(DTG) curves were recorded on a PE-DTG/1700 thermal analyzer with a heating rate of 10 ℃/min. The X-ray powder diffraction patterns were recorded with a Rigaku D/Max-3B X-ray diffractometer, Cu Kα. The average oxidation state of Mn in the Li-Mn-O spinel products was determined by the redox titration with oxalic acid as reducing agent and the hot sulfuric acid as solvent of Li-Mn-O spinel, and the excess oxalate acid was back-titrated by potassium permanganate solution. The cyclic voltammetric(CV) curves of Li-Mn-O spinels were recorded on the CHI660 Electrochemical Workstation with the scan rate of 0.02 mV/s by using the powder microelectrode(PME) as working-electrodes. PMEs used in this work were made from Pt micro-disk electrodes of 0.1 mm in diameter. Pt micro-disk electrode was first chemically etched to form a cavity of tens of micrometers deep and then the cavity was filled with Li-Mn-O spinels powder without any binder and conductive. All cell handing was performed in an argon-filled glove box. Lithium was used as both the negative electrode and the reference electrode, 1 mol/L LiPF6 dissolved in a mixture of propylene carbonate(PC) and dimethoxyethane(DME) (PC∶ME=1∶1, by volume) was used as the electrolyte.
3 Results and discussion
Fig.1 shows the TG and DTA curves of the precursor LiMn(C2O4)(Ac). The TG curve indicates that the mass loss occurs mainly in two steps in the temperature range of 100-487℃. In the first step, the mass loss of 7.31% is associated with the departure of methyl (cal. 7.20%) in the temperature range of 100-190 ℃, and the small exothermic peak is correspondingly observed at around 190℃ in the DTA curve. In the second step, the mass loss of 48.82% in the temperature range of 190-487 ℃ corresponds to the combustion of residual organic constituents (47.87%, calculated according to the Li2Mn2O4 product) in precursor, which accompanies a strong exothermic peak at 274 ℃ in the DTA curve. The total mass loss in the temperature range of 100-487 ℃ is measured as 56.13%, which is in good accordance with the calculated value of 55.07% within the experimental error. These results suggest that the organic elements (C and H) in LiMn(C2O4)(Ac) are completely decomposed in this temperature range. The detailed thermo-decomposed processes are shown in Fig.2. In addition, there is a little mass loss of about 2% between 487 ℃ and 900 ℃, which is resulted from the worse stability of Li-Mn-O spinels with high Li/Mn ratio at high temperature.
Fig.1 TG-DTG curves of LiMn(C2O4) (Ac) precursor measured with heating rate of 10℃/min
Fig.2 Thermo-decomposition process of LiMn(C2O4)(Ac)
Fig.3 shows the powder XRD patterns of the Li-Mn-O samples prepared by sintering the LiMn(C2O4)(Ac) precursor at 450, 500, 550, 600, 700 and 850 ℃. According to the typical XRD patterns of the various Li-Mn-O compounds summarized by Julien et al[17], except for the marked peaks indicating the corresponding impurities, the mainly diffraction peaks can be indexed by the cubic spinel unit cell (Fd3m). For the 450 ℃ sample, a small amount of the orthorhombic LiMnO2 (Pmmn) and tetragonal Li2Mn2O4 (F41/ddm) can be respectively observed from the diffraction peaks at 2θ=25.10? (marked by ▲) and at 2θ=32.76? (marked by ?)[11,17]. When the sintering temperature increases to 500 ℃, the orthorhombic LiMnO2 impure phase disappears, whereas the rock salt Li2MnO3 impurities (C2/m, especially at about 2θ =37.10? and 44.80?, marked by *) emerges when the sintering temperature is above 550 ℃[12,13,17]. Consi- dering 1∶1 Li/Mn ratio in the LiMn(C2O4)(Ac) precursor, it was judged that the 450 ℃ sample mainly consisted of the lithiated-spinel Li2Mn2O4. However, for [Li1+y]tet[Mn2-x- Lix]octO4 spinel series with high Li/Mn ratio, the similar oxygen array even if the different molar fraction and different occupied site fraction (8a or 16d) of lithium, made them difficult to be identified distinctly by the closely similar XRD patterns[17], especially at the disturbance of the phase of Li2MnO3 impurities. As reported by several authors[6,13,17, 20], the cell parameters and the electrochemical properties have more distinct differences among these [Li1+y]tet[Mn2-xLix]octO4 spinel series. For some stoichiometric Li-Mn-O compounds, these differences are summarized in Table 1.
Fig.3 XRD patterns of Li-Mn-O spinel prepared by sintering precursor at various temperatures for 12 h in air
Fig.4 shows the CV curves of the Li-Mn-O spinels obtained by sintering LiMn(C2O4)(Ac) precursor at various temperatures. It is seen from the CV curves that the potentials of Li+ intercalation/ deintercalation (vs Li+/Li) have distinct difference among these Li-Mn-O samples. The data of the cell parameters (calculated from Fig.5 with reference to the cubic spinel unit cell) and potentials of Li+ intercalation/ deintercalation for the Li-Mn-O samples obtained at different sintering temperatures are given in Table 2. It can be seen that the lattice parameter decreases firstly in the sintering temperature range from 450 ℃ to 550 ℃ and then increases in the sintering temperature range from 550 ℃ to 850 ℃. Because of the Jahn-Teller effect of Mn3+ in Li2Mn2O4 for 450 ℃ sample, a slight distortion from cubic to tetragonal unit cell is also observed from the cell parameters (a=8.146 ?, c=8.480 ?, c/a=1.04) calculated from the Miller indices of the tetragonal unit cell. By comparing the data of cell parameters and potential of Li+ intercalation/deintercalation in Table 1 with that in Table 2, the phase structure of the Li-Mn-O samples obtained at different sintering temperatures can be judged as given in Table 3.
From the XRD patterns in Fig.3, the intensities of diffraction peaks of Li2MnO3 increase clearly with the raising sintering temperature, which indicates that the content of Li2MnO3 in the Li-Mn-O spinels increases with the sintering temperature. Clearly, the formation of Li2MnO3 impurities must lead to the variation of the composition of the Li-Mn-O samples because the Li/Mn ratio for Li2MnO3 is as twice times as the nominal Li/Mn ratio in the LiMn(C2O4)(Ac) precursor, and consequently lead to the phase transition of the Li-Mn-O spinels. Fig.5 shows the TG curve of Li2Mn2O4 (450 ℃ sample) in the heating temperature range from 300 ℃ to 850 ℃. It is observed that the mass increases gradually between 320 ℃ and 540 ℃ with about 2.41% increment. Because of the instability of the lithiated-spinel Li2Mn2O4 at high temperature resulted from the Jahn-Teller distortion, it decomposes under the oxidizing conditions of an air atmosphere. However, the mass loss between 540 ℃ and 850 ℃ shown in Fig.5 indicates a more complicated phase transition process.
Table 1 Data of cell parameters and potential of Li+ intercalation/deintercalation for some stoichiometric Li-Mn-O compounds
Table 2 Cell parameters, potential of Li+ intercalation/ deintercalation and average oxidation state of Mn for Li-Mn-O samples obtained at different sintering temperatures
Table 3 Structure properties of Li-Mn-O samples obtained at different sintering temperatures
Fig.4 CV curves of Li-Mn-O spinels prepared by sintering precursor at different temperatures: (a) 450 ℃; (b) 500℃; (c) 550 ℃; (d) 600 ℃; (e) 700 ℃; (f) 850 ℃
Fig.5 TG curve of 450 ℃ sample, measured with heating rate of 10 ℃/min
According to the formation of the Li2MnO3 impurities, the reaction equation can be expressed as
(3-3x-y)/2 Li2Mn2O4+(1-y)/2O2→
[Li1+y]tet[Mn2-xLix]octO4+(1-2x-y)Li2MnO3 (1)
where x is the fraction of Li+ occupied in the octahedral 16d sites, and y is the fraction of Li+ occupied in tetrahedral 8a sites. Here, [Li1+y]tet[Mn2-xLix]octO4 formula was based on the fact that Li not only can substitute partially Mn in the octahedral 16d sites to form the manganese-absent spinels but also can occupy the unoccupied tetrahedral 8a sites to form the lithium-rich spinels. From Eqn.(1), the uptake oxygen leads to the increase of mass, as is confirmed by the TG curve in Fig.5. According to Eqn.(1), it is considered having two cases as follows
1) For the case of 2x+y=1
In this case, Li2MnO3 phase does not form. The oxidization of Li2Mn2O4 is only resulted from the transfer of Li+ from tetrahedral 8a sites to octahedral 16d sites. By substituting y=1-2x into Eqn.(1), as a result, Eqn.(1) can be expressed as
(1-x/2)Li2Mn2O4+xO2→[Li2-2x]tet[Mn2-xLix]octO4 (2)
This reaction equation can also be expressed as an oxygen-rich form:
Li2Mn2O4+δO2→Li2Mn2O4+δ (3)
Clearly, the average oxidation state of Mn in Li2Mn2O4+δ is higher than that in Li2Mn2O4, but the Li/Mn ratio is not varied. With the increasing x value, Li2Mn2O4 can be oxidized and gradually transited to a middle-phase similar to stoichiometric Li4Mn5O12. As shown in Table 3, the 500 ℃ sample should be catego- rized to this case. Because the average oxidation state of Mn is increased, the thermal stability of [Li2-2x]tet[Mn2-xLix]octO4 is improved. According to Eqn.(2), the average oxidation state of Mn, n, can be expressed as
(0≤x≤0.333) (4)
or
(3≤n≤3.8) (5)
Fig.6 shows the functions of x-n and y-n for this case. Therefore, the fraction of Li+ in the octahedral 16d sites can be calculated from the average oxidation state of Mn. For the ideal cubic Li2Mn2O4 (x=0, y=1) in which all of lithium-ions occupy in the tetrahedral 8a sites, n is 3. In the case of x=0.333, [Li2-2x]tet[Mn2-xLix]octO4 exhibits the ideal lithium-rich Li4+yMn5O12 phase (y=1). The maximal value of n could reach 3.8 if the ratio of Li/Mn in [Li2-2x]tet[Mn2-xLix]octO4 would retain at 1:1 until x=0.333. For examples of 450 ℃ sample and 500 ℃ sample, the XRD data in Fig.3 suggest the Li2MnO3 phase does not clearly form. From their average oxidation state of Mn as given in Table 2, it can be estimated that the x of Li+ in the octahedral 16 d sites is ab. 0.06 for 450 ℃ sample and 0.287 for 500 ℃.
Fig.6 Function of average oxidation state of Mn with fraction of Li+ in octahedral 16d sites (x-n) and tetrahedral 8a sites (y-n) for [Li1+y]tet[Mn2-xLix]octO4 spinels (Li:Mn=1, at case of 2x+ y=1)
2) For the case of 2x+y≤1
In this case, Li2MnO3 phase forms. The reaction as Eqn.(1) increases the average oxidation state of Mn and also lowers the Li/Mn ratio in the [Li1+y]tet[Mn2-xLix]octO4 spinel phase. As a result, the thermal stability of [Li1+y]tet[Mn2-xLix]octO4 spinel is further enhanced with the separation of the more stable Li2MnO3. According to the structure properties in Table 3, the 550 ℃ samples should be approximately categorized to this case. From Eqn.(1), the average oxidation state of Mn in the multiphase of [Li1+y]tet[Mn2-xLix]octO4 and Li2MnO3 can be expressed as
((0≤x≤0.333) (6)
Assuming the molar ratio of Li1+y]tet[Mn2-xLix]octO4 spinel to Li2MnO3 phase is m, from Eqn.(1), the value of m can be expressed as
m=1-2x-y (7)
Substituting Eqn.(7) into Eqn.(6), the fractions of Li+ in tetrahedral sites and in octahedral sites can be respectively calculated from
(8)
At the case of m=0, i.e. the Li2MnO3 phase does not form, Eqn.(8) is just identical with Eqn.(5). From Eqn.(8), theoretically, the structure properties (such as phase composition, fraction of Li+ occupied different sites) of [Li1+y]tet[Mn2-xLix]octO4 spinel can be quantitatively analyzed by the data of XRD and the average oxidation state of Mn. The detail for this complex case will be separately discussed in other papers.
It is worth noting that the Li2MnO3 phase begins to form even if the value of x does not reach 0.333. For 550 ℃ sample, assuming that the content of Li2MnO3 phase is zero (m=0), from its average oxidation state of Mn(3.71), the value of x also is only 0.301. Therefore, during the transfer of Li+ from tetrahedral 8a sites to octahedral 16d sites, there is a competition between the individual Li2Mn2O4+δ phase (2x+y=1) and the multiphase (2x+y≤1) of [Li1+y]tet[Mn2-xLix]octO4 and Li2MnO3. Consequently, both of the ideal cubic Li2Mn2O4 (x=0, y=1) and ideal lithium-rich Li4+yMn5O12 phase (y=1) are difficult to be obtained.
In the temperature range of 550-850℃, the TG curve in Fig.5 shows a mass-decreasing process. Note that [Li1+y]tet[Mn2-xLix]octO4 spinel at about 500 ℃ exhibits the stoichiometric Li4Mn5O12-like structure as discussed above. As suggested by Thackeray et al[12, 21], the stoichiometric Li4Mn5O12 would decompose to the more stable LiMn2O4 and Li2MnO3 at temperatures higher than 400 ℃, which is associated with the evacuation of oxygen as follows:
Li4Mn5O12→2LiMn2O4+Li2MnO3+1/2O2 (9)
When the sintering temperature is above 900 ℃, the rock-salt LiMnO2 phase can be formed by the reaction between LiMn2O4 and Li2MnO3:
LiMn2O4+Li2MnO3→3LiMnO2+1/2O2 (10)
From the CV curve of 550 ℃ sample in Fig.4(c), a small redox couple at 3.82 V/3.68 V indicates a little transition from stoichiometric Li4Mn5O12-like structure to LiMn2O4-like structure. For the 700 ℃ sample, a large redox couple at 3.86 V/3.66 V in Fig.4(e) suggests that [Li1+y]tet[Mn2-xLix]octO4 spinel with LiMn2O4-like structure has been largely formed. Because the potential of Li+ intercalation/ deintercalation in the 4 V region is not observed among the 550-700 ℃ samples, the structure of the these samples is in the middle-phase between Li4Mn5O12 and LiMn2O4. In this temperature range, lithium-ions gradually break away from the octahedral 16 d sites to form the Li2MnO3 phase, which makes the value of x gradually decrease and the content of Li2MnO3 phase further increase. Consequently, the average oxidation state of Mn also decreases with the evacuation of oxygen as shown in Table 2. However, from the CV curve of the 850 ℃ sample in Fig.4(f), only is a weak redox couple at 3.21 V/2.53 V observed, which indicates a phase transition from LiMn2O4 phase to the rock-salt LiMnO2 phase of which the electrochemical activity is very poor. These results confirm that the reactions as given in Eqn.(9) and Eqn.(10) are also applicable to [Li1+y]tet[Mn2-xLix]octO4 with the non-stoichiometric Li4Mn5O12-like structure.
4 Conclusions
The composition, structure and electrochemical properties of Li2Mn2O4 are very sensitive to the sintering temperature. By the XRD, CV curves and average oxidation state of Mn, the phase transition process of the Li2Mn2O4 spinel was investigated. The results show that the transfer of Li+ from 8a sites to 16d sites plays a very important role in the phase transition of Li2Mn2O4. As a result, a series of [Li1+y]tet[Mn2-xLix]octO4 spinels can be formed at different sintering temperatures. In addition, a way of determining x in the [Li1+y]tet[Mn2-xLix]octO4 spinel was also demonstrated by average oxidation state of Mn and the content of Li2MnO3.
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Foundation item: Project(20406024) supported by the National Natural Science Foundation of China; Project(76600) supported by the Postdoctoral Science Foundation of Central South University, China
Corresponding author: TANG Xin-cun; Tel: +86-731-8836961; E-mail: tangxincun@163.com
(Edited by LI Xiang-qun)