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pathway (Eqs. (4) and (5)) or the Volmer-Heyrovsky pathway (Eqs. (4) and (6)), both of which involve the adsorption and desorption of Hads on electrode surface [21]. Values of b can be used to evaluate the mechanistic pathways of the HER. If Eq. (4) is the rate-determining step, b can be expected to be around 118 mV/dec. When Eq. (4) occurs rapidly and is followed by a slower electro-desorption......
and compete for resin’s limited surface sites, indicating that the adsorbed iron ions will be part of the energy balance of the system whereby, Fe(II) desorption takes place to accommodate the Sb(III... and Chemical Engineering (IJCCE), 2010, 29: 59-66. [30] NUR T, NGUYEN T C, VIGNESWARAN S, SINGH G, KANDASAMY J. Batch, and column adsorption and desorption of fluoride using hydrous ferric oxide: Solution......
; (5) where KR and α are the Redlich-Peterson constants, and β is the coefficient from 0 to 1. The cyclic adsorption/desorption experiments were conducted... and porphyrin derivatives as building blocks, nitrogen adsorption/desorption measurement was carried out to evaluate the permanent porosity of FcPOP, and the isotherm is provided in Figure 4(a). Obviously......
continuously increased during curing. Based on the DTG curves, the mass loss of all samples can be mainly divided into three steps, corresponding to the desorption of water and the decomposition of hydration... °C can be mainly attributed to the desorption of water in the C-S-H pores and the decomposition of C-S-H gel. As temperature varied from 400 °C to 460 °C, a steep mass loss ranged from 3.1% to 17......
to the formation of oxide-free boundaries and a reduction in the thickness of the oxide, which improved the chemical activity of the Ti surface and promoted sintering densification. TiH2 exhibits high desorption kinetics, and the dehydrogenation steps should be run for enough time to complete the desorption of the hydride from the green parts. Thus, the dehydrogenation process was conducted at 715 °C for 2 h......
)). The Tafel slope of Se-NiCoP-2/CC is 81.6 mV/dec, indicating that its hydrogen evolution process may be followed by the Volmer-Heyrovsky mechanism, and the electrochemical desorption is rate... Yan, MA Fei. Sulfur doping enhanced desorption of intermediates on NiCoP for efficient alkaline hydrogen evolution [J]. Nanoscale, 2020, 12(3): 1985-1993. DOI: 10.1039/ c9nr08583a. [20] QU Mei-jiao......
metallurgica sinica, 2003, 39(1): 89-93. [36] 王伟伟, 龙兴贵. Ti-Mo合金的吸放氢动力学[J]. 核化学与放射化学, 2007, 29(2): 80-84. WANG Wei-wei, LONG Xing-gui. Study on the kinetics for thermal desorption of Ti-Mo Alloy Hydrides[J... R, JONES R M A, et al. Effect of coating morphology on the electron stimulated desorption from Ti-Zr-Hf-V nonevaporable-getter-coated stainless steel[J]. Vacuum, 2012, 86(12): 2035-2039. [50] XIONG Y......
and application of cellular metals and metal foams[J]. Progress in Materials Science, 2001, 46 (6): 559?632. [2] ZEPPELIN F V, HIRSCHER M, STANZICK H, BANHART J. Desorption of hydrogen from blowing......
. Laser-induced explosive boiling during nanosecond laser ablation of silicon[J]. Appl Surf Sci, 2002, 186: 288-292. [14] Hoheisel, Vollmer W, Traeger M. Desorption of metal atoms with laser light......
on the high-temperature capture of HCl gas by dry-injection of calcium-based sorbents [J]. Chemosphere, 2001, 42(5/7): 785-769. [22] CHAI Yi, ZHANG Qiang, HOU Xue-jun. Absorption and desorption of hydrogen......