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decomposition reactions are NH4AlF4 and AlF3(NH4F)0.69, respectively. The three reactions occur at 194.9, 222.5 and 258.4 °C, respectively. Gibbs free energy changes of pertinent materials at the reaction temperatures were calculated. Enthalpy and entropy changes of the three reactions were analyzed by DSC method. Anhydrous aluminum fluoride was prepared. The XRD analysis and mass loss calculation show......
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on the reliability of kinetic parameters of nonisothermal thermoanalytical rate measurement by the widely applied Coats-Redfern(CR) equation. For this purpose, simulated TGA curves were made for reactions with different kinetic models, including chemical, diffusion (Janders) and mixed mechanism at different heating rates. The results show that, for reactions controlled kinetically by one mechanism, all solid......
Photon-Ion Catalysis Synergy Material and Its Application金宗哲,王毅,王圣威,黄丽容摘 要:<正>The co-operation action mechanism and model of photon-ion catalysis synergy material composed of thallium and valency-variable rare earth elements and semiconductor oxide were proposed. The radiation catalysis reactions of water and oxygen assisted by the synergy......
growth rate have been exa-mined.Some electrochemical reactions occurredduring tests and models for describing the cor-rosion fatigue crack growth process in lowstrength of offshore structural steel......
reactions in the history.With the expectation to help catalysis scientists to get better acquaintance with,and gain deeper understanding on this type of compounds as heterogeneous catalysts,the major... reactions have been summarized.Furthermore,the future work which needs to be performed to perceive in depth this kind of important materials as catalysts has been proposed and suggested.We trust......
reactions in the history.With the expectation to help catalysis scientists to get better acquaintance with,and gain deeper understanding on this type of compounds as heterogeneous catalysts,the major... reactions have been summarized.Furthermore,the future work which needs to be performed to perceive in depth this kind of important materials as catalysts has been proposed and suggested.We trust......
. These heavy metals do not only catalyse the surface reactions but generate a more corrosion resistant surface. We perfected the trecation phosphate solution by reducing the sludge, accelerating the phosphating reactions, improving corrosion protection and alkaline resistance. More even and finer grain structures, excellent corrosion resistance were obtained compared to the traditional phosphating......
of Materials and Metallurgy,Northeastern University摘 要:Nd3+-doped Li1.05V3O8 was synthesized by liquid-state reactions combined calcination.The influences of Nd3... capacity,discharge voltage and ion conductivity of the cathode material to some extent.Nd3+ did not participate in the electrochemical reactions and was beneficial to stability of the crystal structure......
property were studied. The light-off temperature of the CO oxidation reaction shifted to a lower temperature due to the water-gas shift (WGS) reactions. The oxidation of C3H8 was enhanced due to the steam reforming (SR) reactions. The steam promoted the C3H8 oxidation and NO reduction in three-way catalytic reaction. The amplitude of stoichiometric window was amplified by the addition of water......