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Catalytic Spectrophotometry for Vanadium Determination Based on Oxidation of Arsenazo Ⅲ by Bichromate何荣桓,王建华摘 要:IntroductionThedeterminationoftracevanadiumreceivedextensiveatentionbecauseofitsincreasingimportanceinbiochemicalandenvironm...关键词:......
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钒(Ⅴ)的测定,结果与认定值相符,相对标准偏差为1.21 %~3.12 %. 关键词:钒(Ⅴ); 动力学光度法; 阻抑作用; 偶氮胂Ⅰ; 次磷酸钠; vanadium (Ⅴ); kinetic spectrophotometry; inhibitory effect; arsenazo Ⅰ; sodium hypophosphite; [全文内容正在添加中] ......
聚乙二醇-偶氮胂Ⅲ萃取光度法测定锆的研究 邓凡政1,董环文1,石影1 (1.淮北煤炭师范学院化学系,淮北235000) 摘要:研究了偶氮胂Ⅲ(ArsenazoⅢ)作萃取剂和显色剂,在聚乙二醇(PEG)-(NH4)2SO4-ArsenazoⅢ体系中的非有机溶剂萃取光度法测定锆.将络合物从0.25mol/L HCl水溶液中萃取到PEG相,其最大吸收波长位于660nm,ε=1.90×104和1.70×104.Zr的线性范围为0~3.0μg/mL和3.0~5.0μg/mL,锆与ArsenazoⅢ的配位比为1:2.方法用于镁锌合金及铝合金中锆的测定,获得满意结果. 关键词:锆; 萃取光度法; 聚乙二醇; 偶氮胂Ⅲ; [全文内容正在添加中] ......
钌催化溴酸钾氧化偶氮胂M反应的研究及其分析应用 曹秋娥1,李崇宁2,李祖碧2 (1.云南大学化学系,云南,昆明,650091;2.云南大学成人教育学院,云南,昆明,650091) 摘要:在硫酸介质中,基于钌对溴酸钾氧化偶氮胂M(AM)褪色的催化作用,建立了测定钌的动力学光度分析法.非催化体系与催化体系在550 nm波长处的吸光度差值,与钌的质量浓度在0~72μg/L范围内,有良好线性关系,检出限为3.78×10-6 g/L.对40 μg/L Ru(Ⅲ)测定11次的标准偏差为2.75%.考察了50多种共存离子的影响,贵金属和大多数常见离子不干扰测定.用于矿样中钌测定的相对标准偏差为0.99......
低分子烃类对吐温80-盐-水液-固析相分离的影响金谷,阚家义中国科技大学化学系!合肥230026摘 要:报导了环己烷,庚烷等的加溶对非离子表面活性剂 (吐温 - 80 )液 -固析相分离的影响 ,使小分子显色剂对甲酰基偶氮变色酸 ( CAp F),偶氮胂 ( Arsenazo )和配合物在低温下就易从盐水溶液相富集到表面活性剂固相 ,萃取率达95%.并对环己烷,庚烷的加溶机理及温度的作用做了探讨.关键词:环己烷;庚烷;吐温-80;液-固相相分离;......
of Arsenazo I and indigo carmine by potassium bromate in sulfuric acid.The absorbances of the catalytic and noncatalytic systems were measured at 510 and610 nm,respectively.Under the optimum conditions......
of arsenazo Ⅲ(AsA Ⅲ) by oxidizing with H2O2 in a pH 4.0 HAc-NaAc buffer solution, and the addition of Triton X-100 can further increase the sensitivity of the reaction and its catalytic extent is linear......
as extractant in kerosene. The metal concentration in the aqueous phase before and after extraction was determined spectrophotometrically by Arsenazo Ⅲ method. The complete equilibration was achieved in 15 min......
as extractant in kerosene. The metal concentration in the aqueous phase before and after extraction was determined spectrophotometrically by Arsenazo Ⅲ method. The complete equilibration was achieved in 15 min......