Solidification pathway and phase transformation behavior in a beta-solidified gamma-TiAl based alloy
来源期刊:JOURNAL OF MATERIALS SCIENCE TECHNOLOG2019年第11期
论文作者:H.Xu X.B.Li W.W.Xing L.Shu Y.C.Ma K.Liu
文章页码:2652 - 2657
摘 要:The phase transformation behavior of an as-cast Ti-42Al-5 Mn(at.%) alloy after subsequent quenching from 1380 ℃ to 1000 ℃ was investigated based on the differential thermal analysis(DTA),electron probe micro analyzer-backscattered electrons(EPMA-BSE),transmission electron microscope(TEM) and X-ray diffraction(XRD).The results show that,the solidification path can be summarized as follows:Liquid→Liquid+β→β→β→α→β+α+γ→βo+α2+γ→βo+γ+α2/γ→βo+γ+α2/γ+βo,sec,with the phase transformation α→β temperature(Tβ)=1311℃,phase transformation γ→β temperature of(Tγsolv)=1231℃,phase transformation α2→α or βo→β temperature(Tα2→α/Tβo→β)=1168 C,eutectoid temperature(Teut)=1132 ℃ and Tα2/γ→βo,sec≈1 120℃.In comparison with Ti-42 Al alloy,the Teut and Tγsolvare slightly increased while both the Tp is decreased obviously by 5% Mn addition.When quenched from the temperature of 1380-1260 ℃,the martensitic transformation β→α’ could occur to form the needlelike martensite structure in β area.This kind of martensitic structure is much obvious with the increase of temperature from 1260℃ to 1380 ℃.When the temperature is below Tγsolv(1231℃),the γ grains would nucleate directly from the β phase.For the temperature slightly lower than Teut(1132℃),the dotted βo,sec phases could nucleate in the lamellar colonies besides the γ lamellae precipitated withinα2 phase.Finally,at room-temperature(RT),the alloy exhibits(po+α2+γ) triple phase with microstructure of βo+lamellae+γ,of which the lamellar structure consists of α2,γ and βo,sec phases.The phase transformation mechanisms in this alloy,involving β→α’,β→γ,α2→α2/γ and α2→βo,sec were discussed.
H.Xu1,2,X.B.Li1,W.W.Xing1,L.Shu1,Y.C.Ma1,K.Liu1
1. Institute of Metal Research,Chinese Academy of Sciences
摘 要:The phase transformation behavior of an as-cast Ti-42Al-5 Mn(at.%) alloy after subsequent quenching from 1380 ℃ to 1000 ℃ was investigated based on the differential thermal analysis(DTA),electron probe micro analyzer-backscattered electrons(EPMA-BSE),transmission electron microscope(TEM) and X-ray diffraction(XRD).The results show that,the solidification path can be summarized as follows:Liquid→Liquid+β→β→β→α→β+α+γ→βo+α2+γ→βo+γ+α2/γ→βo+γ+α2/γ+βo,sec,with the phase transformation α→β temperature(Tβ)=1311℃,phase transformation γ→β temperature of(Tγsolv)=1231℃,phase transformation α2→α or βo→β temperature(Tα2→α/Tβo→β)=1168 C,eutectoid temperature(Teut)=1132 ℃ and Tα2/γ→βo,sec≈1 120℃.In comparison with Ti-42 Al alloy,the Teut and Tγsolvare slightly increased while both the Tp is decreased obviously by 5% Mn addition.When quenched from the temperature of 1380-1260 ℃,the martensitic transformation β→α’ could occur to form the needlelike martensite structure in β area.This kind of martensitic structure is much obvious with the increase of temperature from 1260℃ to 1380 ℃.When the temperature is below Tγsolv(1231℃),the γ grains would nucleate directly from the β phase.For the temperature slightly lower than Teut(1132℃),the dotted βo,sec phases could nucleate in the lamellar colonies besides the γ lamellae precipitated withinα2 phase.Finally,at room-temperature(RT),the alloy exhibits(po+α2+γ) triple phase with microstructure of βo+lamellae+γ,of which the lamellar structure consists of α2,γ and βo,sec phases.The phase transformation mechanisms in this alloy,involving β→α’,β→γ,α2→α2/γ and α2→βo,sec were discussed.
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