Effect of anions on stress corrosion cracking behaviors of ultra-high strength steel 23Co14Ni12Cr3Mo
来源期刊：中南大学学报(英文版)2014年第6期
论文作者：LIU Jian-hua(刘建华) WEN Chen(文陈) YU Mei(于美) LI Song-mei(李松梅) WANG Bing(王兵)
文章页码：2117 - 2124
Key words：23Co14Ni12Cr3Mo; ultra-high strength steel; chloride; sulfate; carbonate; stress corrosion cracking
Abstract: The effects of chloride, sulfate and carbonate anions on stress corrosion behaviors of ultra-high strength steel 23Co14Ni12Cr3Mo were studied by stress corrosion cracking (SCC) test method using double cantilever beam (DCB) specimens. The SCC morphology was observed by using scanning electron microscopy (SEM) and the composition of corrosion products was analyzed by using energy dispersive spectrometer (EDS). The results show that the crack propagates to bifurcation in NaCl and Na2SO4 solution, while the crack in Na2CO3 solution propagates along the load direction. The SCC rate in NaCl solution is the highest, while lower in Na2SO4 solution and little in Na2CO3 solution. From the SEM morphologies, quasi-cleavage fracture was observed in NaCl and Na2SO4 solutions, but intergranular features in Na2CO3 solution. The mechanism of anion effect on SCC of steel 23Co14Ni12Cr3Mo was studied by using full immersion test and electrochemical measurements.
LIU Jian-hua(刘建华), WEN Chen(文陈), YU Mei(于美), LI Song-mei(李松梅), WANG Bing(王兵)
(School of Materials Science and Engineering, Beihang University, Beijing 100191, China)
Abstract:The effects of chloride, sulfate and carbonate anions on stress corrosion behaviors of ultra-high strength steel 23Co14Ni12Cr3Mo were studied by stress corrosion cracking (SCC) test method using double cantilever beam (DCB) specimens. The SCC morphology was observed by using scanning electron microscopy (SEM) and the composition of corrosion products was analyzed by using energy dispersive spectrometer (EDS). The results show that the crack propagates to bifurcation in NaCl and Na2SO4 solution, while the crack in Na2CO3 solution propagates along the load direction. The SCC rate in NaCl solution is the highest, while lower in Na2SO4 solution and little in Na2CO3 solution. From the SEM morphologies, quasi-cleavage fracture was observed in NaCl and Na2SO4 solutions, but intergranular features in Na2CO3 solution. The mechanism of anion effect on SCC of steel 23Co14Ni12Cr3Mo was studied by using full immersion test and electrochemical measurements.
Key words:23Co14Ni12Cr3Mo; ultra-high strength steel; chloride; sulfate; carbonate; stress corrosion cracking
