Hydrothermal synthesis and photoluminescent properties of Li2Sr0.996SiO4:Pr0.0043+ phosphors for white-LED lightings
来源期刊：Journal of Rare Earths2015年第3期
论文作者：周小军 熊兆贤 薛昊 林一森 宋春晓
文章页码：244 - 248
摘 要：Red phosphors, Li2Sr0.996 Si O4: Pr3+0.004, with different hydrothermal conditions were prepared via hydrothermal synthesis and then heat-treatment. The chemical structures of the phosphors were identified with X-ray diffraction（XRD）. Surface morphological features were observed by scanning electron microscopic（SEM） investigation. Spectra of excitation and emission for the phosphors were also obtained by a spectrophotometer. Results showed that the optimum conditions were as follows: p H value of solution was 1–2, reaction temperature was at 180 oC for 24 h. The as-prepared phosphors exhibited two excitation dominant peaks at 451 and 486 nm, attributed to transitions of 3H4→3P2 and 3H4→3P0 of Pr3+, respectively. A narrow emission peak at 610 nm corresponded to the energy level transition of 3P0→3H6 of Pr3+ under excitation of light at 451 nm, which indicated promising candidate red phosphors for blue LED chips.
周小军，熊兆贤，薛昊，林一森，宋春晓
Department of Materials Science and Engineering, Xiamen University
摘 要：Red phosphors, Li2Sr0.996 Si O4: Pr3+0.004, with different hydrothermal conditions were prepared via hydrothermal synthesis and then heat-treatment. The chemical structures of the phosphors were identified with X-ray diffraction（XRD）. Surface morphological features were observed by scanning electron microscopic（SEM） investigation. Spectra of excitation and emission for the phosphors were also obtained by a spectrophotometer. Results showed that the optimum conditions were as follows: p H value of solution was 1–2, reaction temperature was at 180 oC for 24 h. The as-prepared phosphors exhibited two excitation dominant peaks at 451 and 486 nm, attributed to transitions of 3H4→3P2 and 3H4→3P0 of Pr3+, respectively. A narrow emission peak at 610 nm corresponded to the energy level transition of 3P0→3H6 of Pr3+ under excitation of light at 451 nm, which indicated promising candidate red phosphors for blue LED chips.
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