Hydration Products of Cement-silica Fume-quartz Powder Mixture under Different Curing Regimes
来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition2017年第3期
论文作者:何永佳 MAO Ruitao 吕林女 HU Shuguang
文章页码:598 - 602
摘 要:Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement(cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder) hydrated under different curing regimes(standard curing, 90 ℃ steam curing, 200 ℃ and 250 ℃ autoclave curing) were investigated by X-ray diffraction and field emission scanning electron microscope equipped with EDAX system. Results showed that the main hydration products in three kinds of hardened pastes under standard curing condition are all C-S-H gels, CH, and AFt. Under 90 ℃ steam curing condition, the main hydration products of cement-silica fume and cement-silica fume-quartz powder are C-S-H gels, whereas those of cement-quartz powder are C-S-H and CH. Under 200 or 250 ℃ autoclave curing condition, no obvious crystallized CH phase is found in hardened pastes of three kinds of blended cement, and C-S-H gels are transformed into one or more crystalline phases such as tobermorite, jennite, and xonotlite. The chemical composition and morphology of these crystalline phases depend on the composition of mixture and autoclave temperature.
何永佳1,2,MAO Ruitao1,2,吕林女1,3,HU Shuguang1,2
1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology2. School of Materials Science and Engineering, Wuhan University of Technology3. School of Science, Wuhan University of Technology
摘 要:Composition, morphology, and structure of hydration products in hardened pastes of three kinds of blended cement(cement-silica fume, cement-quartz powder and cement-silica fume-quartz powder) hydrated under different curing regimes(standard curing, 90 ℃ steam curing, 200 ℃ and 250 ℃ autoclave curing) were investigated by X-ray diffraction and field emission scanning electron microscope equipped with EDAX system. Results showed that the main hydration products in three kinds of hardened pastes under standard curing condition are all C-S-H gels, CH, and AFt. Under 90 ℃ steam curing condition, the main hydration products of cement-silica fume and cement-silica fume-quartz powder are C-S-H gels, whereas those of cement-quartz powder are C-S-H and CH. Under 200 or 250 ℃ autoclave curing condition, no obvious crystallized CH phase is found in hardened pastes of three kinds of blended cement, and C-S-H gels are transformed into one or more crystalline phases such as tobermorite, jennite, and xonotlite. The chemical composition and morphology of these crystalline phases depend on the composition of mixture and autoclave temperature.
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