Electrochemical degradation of reactive brilliant red X-3B with the（CeO2/C）-β-PbO2-PTFE composite electrode
来源期刊：JOURNAL OF RARE EARTHS2016年第5期
论文作者：孙鹏哲 陈东辉
文章页码：507 - 520
摘 要：The（CeO2/C）-β-PbO2-PTFE composite electrodes modified by graphite powder,cerium oxide powder,polytetrafluoroethylene（PTFE）and the homemade β-PbO2 powder were prepared by the high pressure molding technique.The X-ray diffraction（XRD）was used to test the purity of the homemade β-PbO2 powder.The surface structure and electrical property of electrodes were characterized by using scanning electron microscopy（SEM）and the cyclic voltammetry curves（CV）.Those images indicated that in electrolysis the（CeO2/C）-β-PbO2-PTFE composite electrodes had higher activity than the β-PbO2-PTFE electrodes,as good as the excellent catalytic performance.In the electrode system the composite electrodes were applied to treat reactive brilliant red（RBR）X-3B solution and we studied the degradation influence factors and the reaction mechanism.The results showed that the electrode system was well in treating RBR X-3B solution with the 20%（CeO2/C）-β-PbO2-PTFE composite electrodes at the initial 100 mg/L RBR X-3B concentration,Na2SO4 concentration of 0.35 mol/L,the constant current density of 30 mA/cm!2 and electrolyte pH =2.After electrolytic time of 90 min,the maximum decolorization and chemical oxygen demand（COD）removal rates reached 88.92% and 54.54%.And the decolorization rate of RBR X-3B was in conformity with pseudo-first-order kinetics equation.The RBR X-3B degradation mechanism in the electrochemical oxidation system was used with LC-MS to analyze the possible intermediates and degradation pathway.
孙鹏哲，陈东辉
College of Chemical and Environmental Engineering,Shanghai Institute of Technology
摘 要：The（CeO2/C）-β-PbO2-PTFE composite electrodes modified by graphite powder,cerium oxide powder,polytetrafluoroethylene（PTFE）and the homemade β-PbO2 powder were prepared by the high pressure molding technique.The X-ray diffraction（XRD）was used to test the purity of the homemade β-PbO2 powder.The surface structure and electrical property of electrodes were characterized by using scanning electron microscopy（SEM）and the cyclic voltammetry curves（CV）.Those images indicated that in electrolysis the（CeO2/C）-β-PbO2-PTFE composite electrodes had higher activity than the β-PbO2-PTFE electrodes,as good as the excellent catalytic performance.In the electrode system the composite electrodes were applied to treat reactive brilliant red（RBR）X-3B solution and we studied the degradation influence factors and the reaction mechanism.The results showed that the electrode system was well in treating RBR X-3B solution with the 20%（CeO2/C）-β-PbO2-PTFE composite electrodes at the initial 100 mg/L RBR X-3B concentration,Na2SO4 concentration of 0.35 mol/L,the constant current density of 30 mA/cm!2 and electrolyte pH =2.After electrolytic time of 90 min,the maximum decolorization and chemical oxygen demand（COD）removal rates reached 88.92% and 54.54%.And the decolorization rate of RBR X-3B was in conformity with pseudo-first-order kinetics equation.The RBR X-3B degradation mechanism in the electrochemical oxidation system was used with LC-MS to analyze the possible intermediates and degradation pathway.
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