Effect of cerium on the cleanliness of spring steel used in fastener of high-speed railway
来源期刊:Journal of Rare Earths2014年第8期
论文作者:刘延强 王丽君 周国治
文章页码:759 - 766
摘 要:The effects of Ce addition on the quantity, size, distribution of inclusions and the content of oxygen, sulfur and other hazardous residual elements in spring steel used as fastener in high speed railway were investigated by metallographic examination, SEM-EDS and composition analysis. The results indicated that the contents of oxygen decreased with the addition of Ce([Ce]<0.1%) and the content of sulfur continually decreased with increasing content of Ce([Ce]<1.2%). However, with the further increase of Ce element addition, the content of [O] and T[O] began to increase. The content of Ce corresponding to the lowest [O] and T[O] lied in the range of 0.10%–0.13% and 0.045%–0.065%, respectively. The addition of Ce in spring steel resulted in the formation of rare earth oxides/oxysulfides and decreased the size of inclusions to less than 3 μm in globular or spheroid shape. Moreover, the residual harmful elements(As, P, Pb and Sn) were found to exist in the Ce-containing inclusions, which had proved that the Ce addition could capture the residual elements and suppress their precipitation behaviors in the grain boundary.
刘延强1,2,王丽君1,2,周国治1,2
1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing2. Department of Physical Chemistry,School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing
摘 要:The effects of Ce addition on the quantity, size, distribution of inclusions and the content of oxygen, sulfur and other hazardous residual elements in spring steel used as fastener in high speed railway were investigated by metallographic examination, SEM-EDS and composition analysis. The results indicated that the contents of oxygen decreased with the addition of Ce([Ce]<0.1%) and the content of sulfur continually decreased with increasing content of Ce([Ce]<1.2%). However, with the further increase of Ce element addition, the content of [O] and T[O] began to increase. The content of Ce corresponding to the lowest [O] and T[O] lied in the range of 0.10%–0.13% and 0.045%–0.065%, respectively. The addition of Ce in spring steel resulted in the formation of rare earth oxides/oxysulfides and decreased the size of inclusions to less than 3 μm in globular or spheroid shape. Moreover, the residual harmful elements(As, P, Pb and Sn) were found to exist in the Ce-containing inclusions, which had proved that the Ce addition could capture the residual elements and suppress their precipitation behaviors in the grain boundary.
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