简介概要

Synthesis and Solution Properties of Comb-like Acrylamide Copolymers

来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition2012年第6期

论文作者:罗霄

文章页码:1105 - 1109

摘    要:A comb-like acrylamide copolymer (HCJ-1) was synthesized by using aqueous free radical polymerization of acrylamide (AM) as main monomer and ether carboxylate as functional monomer. The copolymers were characterized with FT-IR and SEM. The SEM results show that the molecular structure of copolymer is extended in salt water. It is proved that the copolymer shows good salt resistance.The solution properties of HCJ-1 were studied and compared with those of partially hydrolyzed polyacrylamide (HPAM). The experimental results show that the obtained HCJ-1, compared with HPAM, exhibits a dramatic enhancement in the salt-resistant properties. The apparent viscosity retention rate of 1.5 g/L HCJ-1 aqueous solution and salt solution after 180 days at 60 ℃ are 70.6% and 64.5%, respectively, exhibiting good thermal stability. In addition, HCJ-1 solution also displays the excellent shearing resistance. In a word, the experimental results show the HCJ-1 is a promising profiling agent for high salinity reservoir.

详情信息展示

Synthesis and Solution Properties of Comb-like Acrylamide Copolymers

罗霄

School of Petroleum Engineering, Southwest Petroleum University

摘 要:A comb-like acrylamide copolymer (HCJ-1) was synthesized by using aqueous free radical polymerization of acrylamide (AM) as main monomer and ether carboxylate as functional monomer. The copolymers were characterized with FT-IR and SEM. The SEM results show that the molecular structure of copolymer is extended in salt water. It is proved that the copolymer shows good salt resistance.The solution properties of HCJ-1 were studied and compared with those of partially hydrolyzed polyacrylamide (HPAM). The experimental results show that the obtained HCJ-1, compared with HPAM, exhibits a dramatic enhancement in the salt-resistant properties. The apparent viscosity retention rate of 1.5 g/L HCJ-1 aqueous solution and salt solution after 180 days at 60 ℃ are 70.6% and 64.5%, respectively, exhibiting good thermal stability. In addition, HCJ-1 solution also displays the excellent shearing resistance. In a word, the experimental results show the HCJ-1 is a promising profiling agent for high salinity reservoir.

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