Synthesis and crystal structures of La（Ⅲ）,Y（Ⅲ） complexes of homoveratric acid with 1,10-phenanthroline
来源期刊：Journal of Rare Earths2010年第1期
论文作者：李花琼 咸会朵 赵国良
文章页码：7 - 11
摘 要：Two three-dimensional complexes Ln（DMPA）3phen2（HDMPA=3,4-dimet hoxyphenylacetic acid,homoveratric acid;Ln=La,Y;phen=1,10-phenanthroline） were synthesized under hydrothermal conditions and characterized with IR and emission spectra.The crystal structures were determined with single crystal X-ray diffraction method.The two compounds were isostructural,and 3D supramolecule architectures were formed by hydrogen bonds and π-π stacking interactions.They strongly emitted upon excitation due to π→π transition of the ligands.
李花琼1,2，咸会朵1,2，赵国良1,2
1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Institute of Physical Chemistry,Zhejiang Normal University2. College of Chemistry and Life Science,Zhejiang Normal University,Jinhua 321004
摘 要：Two three-dimensional complexes Ln（DMPA）3phen2（HDMPA=3,4-dimet hoxyphenylacetic acid,homoveratric acid;Ln=La,Y;phen=1,10-phenanthroline） were synthesized under hydrothermal conditions and characterized with IR and emission spectra.The crystal structures were determined with single crystal X-ray diffraction method.The two compounds were isostructural,and 3D supramolecule architectures were formed by hydrogen bonds and π-π stacking interactions.They strongly emitted upon excitation due to π→π transition of the ligands.
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