FeO-SiO2-CaO-MgO系高镁炉渣粘度的测定
来源期刊:中南大学学报(自然科学版)1997年第4期
论文作者:曾德文 李作刚 刘海霞 张传福
文章页码:343 - 346
关键词:炉渣; 粘度; 氧化镁mSO2,ωFe3O4
Key words:slag; viscosity; MgO
摘 要:测定了合成的不同成份的FeO-CaO-MgO系炉渣的粘度,得知:在炉渣中,当mFe/mSO2为1.2~1.5,ωMgO为6%~9%,ωFe3O4为3%~4%,ωCaO为0~9%,温度范围为1250~1450℃时,炉渣粘度随ωFe/ωSiO2和ωCaO的升高而降低,随着ωMgO的升高而增大;在1350℃以上时,上述变化关系则不明显.对于闪速炼镍所采用的FeO-SiO2-CaO-MgO系炉渣,在一般的冶炼操作温度(1300~1350℃)下,当渣中ωMgO高达6%~8%时,仍可获得流动性能良好的渣;当ωMgO在9%以上时,则渣的粘度迅速上升以致不适合于冶炼.同时,在炉渣总量不变的情况下,在一定的范围内通过减少SiO2的加入量和补加CaO含量可使炉渣粘度得到改善.
Abstract: Viscosities of various slags of FeO-SiO2-CaO-MgO system are determinated in this paper. The results show that slag viscosity is decreased with the increase of mFe/mSiO2 ratio and CaO content and with the decrease of MgO content under the range of slag contents: mFe/mSiO2 1. 2~1. 5, ωMgO6%~9%,ωFe3O4 3%~ 4%, ωCaO 0~9%,temperature range of 1250~1450℃, of which the relations are not distinct above 1350 ℃. When the MgO content exceeds 9%, the slag viscosity is increased abrupty to 0. 9~1. 3 Pa· s at ordinarily smelting temperature of 1300℃, which means the MgO content should not exceed 9% in practical operation in order to obtain a good mobility of slag. Meanwhile,low-viscosity slag can be obtained by adding CaO and lowering SiO2 content without increasing the total weight of slag,