Phase and structure of polycrystal Sr0.69La0.31F2.31+SrS solid electrolyte material
来源期刊:中国有色金属学报(英文版)1999年第3期
论文作者:田彦文 马平 张新 翟玉春
文章页码:541 - 545
Key words:X-ray diffraction; electron probe; polycrystal Sr0.69La0.31F2.31+SrS material; phase structure
Abstract: The phase and the structure of polycrystal material, which was prepared by calcining the co-precipitated fluoride powder of Sr and La with a ratio of 0.69∶0.31 mixed with SrS powder, were investigated by X-ray diffraction and electron probe scanning. In the materials, three phases were found, they are Sr0.69La0.31F2.31 solid solution phase with a pure SrF2 cubic structure whose lattice constant is 5.843 A , SrS single phase with a NaCl cubic structure, and an unknown phase that is produced by the interaction of SrS and co-precipitated powder. It was also found that SrS has no influence on the structure of Sr0.69La0.31F2.31 solid solution.