Magnetocaloric Effect in MnCo1-xAlxGe Compounds
来源期刊:JOURNAL OF MATERIALS SCIENCE TECHNOLOG2009年第6期
论文作者:O. Tegus Yirgeltu
文章页码:781 - 784
摘 要:The effects of substitution of Al for Co on magnetic and magnetocaloric properties of MnCo1-xAlxGe (x=0.00, 0.03, 0.05, 0.08, 0.10, 0.13, 0.15, and 0.20) compounds have been investigated by X-ray diffraction (XRD) and magnetization measurements. XRD exhibits that MnCo1-xAlxGe compounds crystallize in the orthorhombic TiNiSi-type structure for x≤0.03 and in the hexagonal Ni2In-type crystal structure for x>0.03. Magnetic measurements show that the Curie temperature can be tuned between 286 and 347 K by changing the Co/Al ratio. The maximum magnetic entropy change determined from the isothermal magnetization measurement by Maxwell relation reaches 1.52 J/(kgK) for x=0.08 in a field change from 0 to 1.5 T around 310 K.
O. Tegus,Yirgeltu
Inner Mongolia Key Laboratory for Physics and Chemistry of Functional Materials, Inner Mongolia Normal University
摘 要:The effects of substitution of Al for Co on magnetic and magnetocaloric properties of MnCo1-xAlxGe (x=0.00, 0.03, 0.05, 0.08, 0.10, 0.13, 0.15, and 0.20) compounds have been investigated by X-ray diffraction (XRD) and magnetization measurements. XRD exhibits that MnCo1-xAlxGe compounds crystallize in the orthorhombic TiNiSi-type structure for x≤0.03 and in the hexagonal Ni2In-type crystal structure for x>0.03. Magnetic measurements show that the Curie temperature can be tuned between 286 and 347 K by changing the Co/Al ratio. The maximum magnetic entropy change determined from the isothermal magnetization measurement by Maxwell relation reaches 1.52 J/(kgK) for x=0.08 in a field change from 0 to 1.5 T around 310 K.
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