化学光谱测定天然水中超微量金属元素
来源期刊:中南大学学报(自然科学版)1984年第4期
论文作者:谭书香 沈汇
文章页码:61 - 70
关键词:微量金属元素; 天然水; 浓度范围; 标准偏差; 钙镁含量; 内标元素; 同时测定; 有害金属元素; 变动系数; 偏硼酸
摘 要:本文在薄炭圆盘技术的基础上,研究了天然水中钙镁对所测定十四个超微量金属元素的影响。采用外加基体的方法,可消除钙镁的影响。检测限对不同元素分别为n×10-2—n×10-4毫克/升,在n×10-2毫克/升的浓度范围,十次测定的变动系数小于25%。
Abstract: In this paper, on the basis of thin carbon disc technique, the effects of calcium and magnesium in the natural water on the 14 kinds of metallic elements in sub-microgram which were measured have been studied. These effects can be eliminated by the adoption of additional matrix method. The detection limits for different elements are between n×10-2-n×10-4mg/litre respectively. When the concentration range is n×l0-2mg/litre, the standard deviation in 10 tests is less than 5 and the coefficient of variation is less than 25%.