氮离子注入及DLC涂层对Ti6Al7Nb合金在人工唾液中微动磨损性能的影响

来源期刊:中国有色金属学报(英文版)2017年第5期

论文作者:郑新颖 张雅蓉 张保荣

文章页码:1071 - 1080

关键词:Ti6Al7Nb合金;离子注入;DLC涂层;微动磨损行为

Key words:Ti6Al7Nb alloy; ion implantation; diamond-like carbon coating; fretting wear behavior

摘    要:通过往复滑动微动磨损实验研究Ti6Al7Nb合金、氮离子注入Ti6Al7Nb合金、DLC涂层Ti6Al7Nb合金在人工唾液环境下的磨损性能。运用X射线衍射分析、拉曼光谱分析、三维轮廓分析、扫描电镜形貌和摩擦动力学行为分析等方法,详细讨论了表面改性层的磨损特性。结果表明:随着氮离子浓度的增加,Ti6Al7Nb合金的抗微动磨损性能提高。具有DLC涂层的低氮离子注入Ti6Al7Nb合金显示出良好的抗微动磨损性。此外,由于其特殊的结构,DLC涂层组具有更好的耐腐蚀性能。在人工唾液环境下,DLC涂层Ti6Al7Nb合金组相比氮离子注入Ti6Al7Nb合金组具有更好的抗磨损性能。

Abstract: The tribology behaviors of Ti6Al7Nb, its alloy with N-ion implantation, and its alloy with diamond-like carbon (DLC) coating were investigated in artificial saliva. Fretting wear tests of untreated, N-ion implanted and DLC coated Ti6Al7Nb alloys plate against a Si3N4 ball were carried out on a reciprocating sliding fretting wear test rig. Based on the analysis of X-ray diffraction, Raman spectroscopy, 3-D profiler, SEM morphologies and frictional kinetics behavior analysis, the damage behavior of surface modification layer was discussed in detail. The results indicated that the fretting wear behavior of Ti6Al7Nb alloy with N-ion implantation was increased with the dose increase of the implanted nitrogen ions. Moreover, the DLC-coated Ti6Al7Nb alloy with low ion implantation could improve the fretting wear behavior greatly. In addition, the Ti6Al7Nb with DLC coating had better corrosion resistance due to the special compact structure. All results suggested that the Ti6Al7Nb with DLC coating had better wear resistance than that with N-ion implantation in artificial saliva.

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