FORMATION AND CRYSTALLIZATION OF LEAD HALIDE BASED GLASSES
来源期刊:Journal Of Wuhan University Of Technology Materials Science Edition1998年第2期
论文作者:程继健
文章页码:9 - 15
摘 要:<正>A series of new glass compositions based onPbX2(X: Cl, Br or I) have heen studied. Binary andternary glasses resulted from the association of PbI2 Pb-Cl2 AgI, KCl and KBr. By means of differential scan-ning calorimetry (DSC), the mechanism and kinetics ofcrystallixation process were studied. X-ray diffractionstudies demonstrate that there is the formation of compli-cated crystalline phases in crystallized lead iodide basedglasses. By heat treating halide glasses of appropriatecomposition under adequate heating temperature and dura-tion, the lead iodide based glasses could be converted intoglass-ceramics with microcrystal size less lμm of whichmechanical properties are improved.
程继健
摘 要:<正>A series of new glass compositions based onPbX2(X: Cl, Br or I) have heen studied. Binary andternary glasses resulted from the association of PbI2 Pb-Cl2 AgI, KCl and KBr. By means of differential scan-ning calorimetry (DSC), the mechanism and kinetics ofcrystallixation process were studied. X-ray diffractionstudies demonstrate that there is the formation of compli-cated crystalline phases in crystallized lead iodide basedglasses. By heat treating halide glasses of appropriatecomposition under adequate heating temperature and dura-tion, the lead iodide based glasses could be converted intoglass-ceramics with microcrystal size less lμm of whichmechanical properties are improved.
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