Hydrothermal Synthesis,Crystal Structure and Properties of Inorganic-Organic Hybrid Materials Based on Diphosphopentamolybdate
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2008年第3期
论文作者：靳素荣
文章页码：407 - 410
摘 要：The compound of diphosphopentamolybdate{[Cu（en）（Hen）] 2 [P 2 Mo 5 O 23 ]}?3H 2 O [en=ethylenediamine]had been obtained from the hydrothermal method and characterized by single crystal X-ray diffraction,elemental analysis,FT-IR,and thermogravimetric analysis.The structure consist of[P 2 Mo 5 O 23 ]6- clusters anions,complex[Cu（en）（Hen）]3+cations and crystallization water molecules,which are held together to a two-dimensional framework.The most interesting feature of the compound is that two nitrogen atoms are both coordinated with Cu（Ⅱ）in one ethylenediamine molecule,for the other ethylenediamine molecule,only one nitrogen atom is towards Cu（Ⅱ）and the other nitrogen atom is protonated and formed Hen+.
靳素荣
摘 要：The compound of diphosphopentamolybdate{[Cu（en）（Hen）] 2 [P 2 Mo 5 O 23 ]}?3H 2 O [en=ethylenediamine]had been obtained from the hydrothermal method and characterized by single crystal X-ray diffraction,elemental analysis,FT-IR,and thermogravimetric analysis.The structure consist of[P 2 Mo 5 O 23 ]6- clusters anions,complex[Cu（en）（Hen）]3+cations and crystallization water molecules,which are held together to a two-dimensional framework.The most interesting feature of the compound is that two nitrogen atoms are both coordinated with Cu（Ⅱ）in one ethylenediamine molecule,for the other ethylenediamine molecule,only one nitrogen atom is towards Cu（Ⅱ）and the other nitrogen atom is protonated and formed Hen+.
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