若干熔盐相图三元中间化合物的形成规律及其实验验证①
来源期刊:中国有色金属学报1996年第1期
论文作者:康德山 王学业 詹千宝 姚树文 陈念贻
文章页码:32 - 35
关键词:熔盐相图; 三元化合物; 形成规律; CsCI · MnSO4
Key words:molten salt phase diagram; ternary compounds; forming criterion; CsCl·MnSO4
摘 要:运用化学键参数与模式识别或人工神经网络相结合,研究若干熔盐相图中三元化合物的形成规律和形成判据。在此基础上,预报若干未知熔盐相图,结果表明CsCI和MnSO4间有1:1化合物,经合成、X射线分析和相图测量,证实CsCI ·MnSO4存在。
Abstract: By chemical bond parameters and pattern recognition or artificial neural network method,the reg-ularity and criterion of formability of ternary intermediate compounds in some molten salt phase diagrams have been studied. Predicted results indicated that the Cs,Mn|Cl,SO4 system could form anew ternary compound CsCl·MnSO4,which was confirmed by X-ray diffraction and the experimental liquidus measure of a cross section of phase diagram in CsCl-MnSO4 system.