Preparation of CeB6 nano-powders by self-propagating high-temperature synthesis（SHS）
来源期刊：Journal of Rare Earths2011年第10期
论文作者：豆志河 张廷安 刘燕 郭永楠 赫冀成
文章页码：986 - 990
摘 要：CeB6 powders were prepared by high-temperature self-propagating synthesis（SHS） in which CeO2,B2O3 and Mg were taken asreactants.The adiabatic temperature and dynamics of SHS reactions were investigated.The SHS reaction products and leached products werecharacterized by X-ray diffraction（XRD） and scanning electron microscopy（SEM）.The results indicated that the adiabatic temperature ofMg-B2O3-CeO2 reaction system was rather higher than 1800 K to make the reaction propagate by itself,and the apparent activation energy（Ea）and reaction order（n） of exothermic peak on Mg-B2O3-CeO2 differential scanning calorimetry（DSC） curve were 23.03 kJ/mol and 1.31,respectively.The apparent activation energy was lower,so the reaction occurred easily.The SHS products consisted of MgO,CeB6 and littleMg3B2O6.The leached products consisted of single CeB6 phase and its purity was higher than 99.0%,and the average particle sizes of CeB6were smaller than 150 nm.
豆志河，张廷安，刘燕，郭永楠，赫冀成
Key Laboratory for Ecological Utilization of Multimetallic Mineral(Ministry of Education),Northeastern University
摘 要：CeB6 powders were prepared by high-temperature self-propagating synthesis（SHS） in which CeO2,B2O3 and Mg were taken asreactants.The adiabatic temperature and dynamics of SHS reactions were investigated.The SHS reaction products and leached products werecharacterized by X-ray diffraction（XRD） and scanning electron microscopy（SEM）.The results indicated that the adiabatic temperature ofMg-B2O3-CeO2 reaction system was rather higher than 1800 K to make the reaction propagate by itself,and the apparent activation energy（Ea）and reaction order（n） of exothermic peak on Mg-B2O3-CeO2 differential scanning calorimetry（DSC） curve were 23.03 kJ/mol and 1.31,respectively.The apparent activation energy was lower,so the reaction occurred easily.The SHS products consisted of MgO,CeB6 and littleMg3B2O6.The leached products consisted of single CeB6 phase and its purity was higher than 99.0%,and the average particle sizes of CeB6were smaller than 150 nm.
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