Characterization and Luminescence Properties of a New Europium(Ⅲ) Complex with a Macrocyclic Ligand
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2010年第6期
论文作者：吴起峰 胡学雷
文章页码：987 - 990
摘 要：The title compound（13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.3.1.111,15]-triaconta-l（29）,2,9,11,13,15（30）,16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30）-bis（nitrato-O,O）-Europium（Ⅲ） nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,respectively.The crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737（2） nm,b=14.333（1） nm,c=19.388（2） nm,β = 91.804（1）°,Mr= 850.4,V= 6.5929（8） nm3,R= 0.0333,wR= 0.0936.At room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3+ ion.
吴起峰，胡学雷
Key Laboratory of Green Chemical Process of Ministry of Education-Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology,Wuhan Institute of Technology
摘 要：The title compound（13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.3.1.111,15]-triaconta-l（29）,2,9,11,13,15（30）,16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30）-bis（nitrato-O,O）-Europium（Ⅲ） nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,respectively.The crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737（2） nm,b=14.333（1） nm,c=19.388（2） nm,β = 91.804（1）°,Mr= 850.4,V= 6.5929（8） nm3,R= 0.0333,wR= 0.0936.At room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3+ ion.
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