Effect of crystallization on corrosion resistance of Cu52.5Ti30Zr11.5Ni6 bulk amorphous alloy
来源期刊:中国有色金属学报(英文版)2007年第4期
论文作者:檀朝桂 蒋文娟 吴学庆 王秀锋 林建国
文章页码:751 - 751
Key words:amorphous materials; crystallization; corrosion behavior; polarization
Abstract: The effects of crystallization on the corrosion resistance of a Cu52.5Ti30Zr11.5Ni6 bulk amorphous alloy in 1 mol/L HCl, and 6 mol/L NaOH solutions were studied. The amorphous alloy was identified by differential thermal analysis(DSC) and by X-ray diffraction(XRD). The partially and fully crystallized alloys were prepared by controlling the annealing temperatures at 738 and 873 K for 1 and 12 min, respectively, and the corrosion resistances of those annealed alloys were compared with that of the amorphous alloy by immersion test and potentiodynamic measurements in 1 mol/L HCl and 6 mol/L NaOH solutions. The results show that the partially crystallized alloy exhibits high corrosion resistance, whereas full crystallization results in deteriorated corrosion resistance compared with that of the as-cast amorphous alloy.
基金信息:the National Natural Science Foundation of China
the Provincial Science and Technology Department Foundation of Hunan, China