Aluminum doping and dielectric properties of silicon carbide by CVD
来源期刊：中国有色金属学报(英文版)2007年增刊第1期(Part ⅡB)
论文作者：李智敏 苏晓磊 罗发 朱冬梅 周万城
文章页码：858 - 861
Key words：silicon carbide; aluminum doping; dielectric properties; chemical vapour deposition
Abstract: Cubic β-SiC coating was grown onto the graphite substrate by the normal pressure chemical vapor deposition using CH3SiCl3 (MTS) as a source precursor at 1 150 ℃. But the hexagonal Al4SiC4 phase was generated in the doped process with trimethylaluminium (TMA) as the dopant. Microstructure of the deposit coating as-prepared was characterized by scanning electron microscope (SEM), which consists of spherical particles with a very dense facet structure. The real component of permittivity ε′ and dielectric loss tanδ of the coatings undoped and doped by TMA were carried out by a vector networ, k analyzer in the microwave frequency ranges from 8.2 GHz to 12.4 GHz. The results show that both of them have low values, and doped coating has lower ε′ and tan δ than undoped one due to the existence of Al4SiC4 impurity phase, which indicates that the desired Al/SiC solid solution at 1 150 ℃ in a normal argon atmosphere is not produced.
基金信息：the National Natural Science Foundation of China
